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lower critical solution temperature (LCST); temperature Tu is an upper consolute temperature, or upper critical solution temperature (UCST) At temperatures between TL and Tu, LLE is possible; for T < TL and T > Tu, a single liquid phase is obtained for the full range of compositions The consolute points are analogous to the liquidlgas critical point of a pure fluid; they are limiting states of two-phase equilibrium for which all properties of the two equilibrium phases are identical Actually, the behavior shown on Fig 1412(a) is infrequently observed; the LLE binodal curves are often interrupted by curves for yet another phase transition When the binodal curves intersect the freezing curve, only a UCST can exist [Fig 1412(b)]; when they intersect the VLE bubblepoint curve, only an LCST can exist [Fig 1412(c)]; when they intersect both, no consolute point exists, and a fourth type of behavior is observed14 Thus it is apparent that real systems exhibit a diversity of LLE behavior The thermodynamic basis for calculation or correlation of LLE is an expression for G E / ~ ~ , from which activity coefficients are derived The suitability of a particular expression is determined by its ability to accommodate the various features illustrated by Fig 1412 This is a severe test, because, unlike their role in low-pressure VLE where they represent corrections to Raoult's law, the activity coefficients here are the only thermodynamic contribution to an LLE calculation

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FileWriter creates a Writer that you can use to write to a file Its most commonly used constructors are shown here: FileWriter(String filePath)

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I4~comprehensive treatment of LLE is given by J M SBrensen,T Magnussen, P Rasmussen, and Aa Fredenslund, FluidPhaseEquilibria, vol 2, pp 297-309,1979; vol 3, pp 47-82,1979; vol 4, pp 151-163,1980 For a compilation Liquid-Liquid Equilibrium Data Collection, of data see W Arlt, M E A Macedo, P Rasmussen, and J M S~rensen, Chemistry Data Series, vol V, Parts 1 4 , DECHEMA, Frankfurtmain, 1979-1987

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Of course, unless the style is bound into a document related to the defined rules, nothing will be seen, so a full example is presented here, with a rendering shown in Figure 4-7:

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FileWriter(String filePath, boolean append) FileWriter(File fileObj) They can throw an IOException or a SecurityException Here, filePath is the full path name of a file, and fileObj is a File object that describes the file If append is true, then output is appended to the end of the file Creation of a FileWriter is not dependent on the file already existing FileWriter will create the file before opening it for output when you create the object In the case where you attempt to open a read-only file, an IOException will be thrown The following example is a character stream version of an example shown earlier when FileOutputStream was discussed This version creates a sample buffer of characters by first making a String and then using the getChars( ) method to extract the character array equivalent It then creates three files The first, file1txt, will contain every other character from the sample The second, file2txt, will contain the entire set of characters Finally, the third, file3txt, will contain only the last quarter // Demonstrate FileWriter import javaio*; class FileWriterDemo { public static void main(String args[]) throws Exception { String source = "Now is the time for all good men\\n" + " to come to the aid of their country\\n" + " and pay their due taxes"; char buffer[] = new char[sourcelength()]; sourcegetChars(0, sourcelength(), buffer, 0); FileWriter f0 = new FileWriter("file1txt"); for (int i=0; i < bufferlength; i += 2) { f0write(buffer[i]); } f0close(); FileWriter f1 = new FileWriter("file2txt"); f1write(buffer); f1close(); FileWriter f2 = new FileWriter("file3txt"); f2write(buffer,bufferlengthbufferlength/4,bufferlength/4); f2close(); } }

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144 Liquid/Liquid Equilibrium (LLE)

<!DOCTYPE html> <html> <head> <meta http-equiv="Content-Type" content="text/html; charset=utf-8"> <title>Linked Styles</title> <link rel="stylesheet" href="sitestylecss" type="text/css" > </head> <body> <div id="page"> <h1>HTML with Linked Style</h1> <p>Cascading Style Sheets 21 as defined by the <a href="http://wwww3org">W3C</a> provides powerful page layout facilities The technology depends on correct markup so make sure you get that right too!</p> </div> </body> </html>

CSS is, at least theoretically, not the only style technology we could use, though as it stands, by default, most browsers assume that CSS is being used We set type to be specific but that may get a bit redundant The HTML specification suggests you can set a default

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