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humidity data corroborated experimental ndings regarding the effect of the variables studied on tablet stability [180] It is known that hard gelatin capsule brittleness is a function of moisture content A study has been carried out to indicate that the brittleness of empty capsules occurred at humidities below 40% Mexitil-loaded capsules exhibited a similar pro le The SDMT model was employed to estimate the nal relative humidity for the Mexitil/gelatin capsule system and results were presented to demonstrate the general applicability of the SDMT model for predicting the incidence of brittleness problems and for the formulation to ensure the absence of brittleness [181] The sorption of two weak acids (warfarin and thiopentone) and two weak bases (chlorpromazine and diltiazem) into PVC infusion bags was described by a constant partition model.

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In this process, a preform is produced (usually by injection molding injection stretch blow molding) that is shorter than the nal container During the blowing step, a stretch rod stretches the preform in the vertical direction as it is expanded in the radial direction by blowing Biaxial orientation can signi cantly improve the strength and barrier properties of the container Coextrusion blow molding is often used to produce multilayer plastic containers A multilayer parison is produced, and subsequent operations are identical to ordinary blow molding Reuse of ash is more dif cult since it will be multilayer In many cases, the ash is used in an inner layer in the container, either alone or combined with other recycled plastic High-density polyethylene (HDPE) laundry product bottles, for example, routinely are made with a three-layer structure in which the inner layer contains ash blended with postconsumer recycled HDPE.

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Multilayer injection blow-molded containers have been available for a much shorter time than multilayer extrusion blow-molded containers, as development of the process was more dif cult However, these too are now available A prominent example is multilayer polyethylene terephthalate (PET)-based ketchup bottles, which contain three layers of PET, and two layers of ethylene vinyl alcohol (EVOH) as an oxygen barrier When containers will be exposed to elevated temperatures, such as in packaging of hot- lled products, container distortion may be a problem, especially for biaxially oriented bottles In this case, a subsequent heat-setting operation may be used to reduce thermal stress and minimize deformation on subsequent exposure to elevated temperatures For many products, the labels are placed into the empty mold and sealed to the container during the molding process (in-mold labeling).

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PVC water partition coef cients were obtained using three different methods: equilibrium values for sorption into PVC bags, the sorption versus pH relationship, and partition into PVC strips The data were compared with similar values derived from a liquid liquid partition system and different organic solvents (octanol, dichloromethane, carbon tetrachloride, and hexane) Octanol is the preferred solvent, and it is suggested that octanol water partition data can be used to predict sorption behavior [182] Reports have shown that changes in the hardness of tablets composed of lactose and cornstarch were due to variation of the moisture content.

This eliminates the need for a subsequent labeling step and produces somewhat recessed labels with a better appearance, including improved scuff resistance In-mold labeling is used most often with extrusion blow molding but can also be used with injection molding..

8. Launch Acrobat Distiller. The watched folder can be identified either before or after the network connection. In this example, I first established my network connection, and now I need to set up the watched folder. 9. Create a watched folder. The folder I created earlier is just a folder or directory on my hard drive. To make this folder a watched folder, I need to choose Settings Watched Folders and select the folder to be watched. When the Acrobat Distiller - Watched Folders dialog box appears, I click the Add button, which opens the Browse for Folder dialog box shown in Figure 5-30. I select the folder and click OK in the dialog box. When I return to the Watched Folder dialog box, the new folder name is displayed in the watched folder list. 10. Examine the watched folder. When I return to my desktop and open the Acro5 Bible folder, I double-check it to be certain Distiller has created the subfolders necessary to make this a watched folder, as shown in Figure 5-31. If you find the In and Out subfolders within the watched folder, you know Distiller will monitor this folder.

Further it was shown that the hardness of the tablets in moisture-semipermeable packages (such as strip packs and press-through packs with or without an overwrap lm) could be predicted by an iterative calculation procedure through a mathematical model based on the physicochemical properties of the tablets and the moisture permeabilities of the packaging materials [183] In another study by the same research group, moisture and temperature were used to predict the shelf-life of packaged tablets Cognizance was taken of the unctuations of temperature and relative humidity during prolonged storage A sugar-coated tablet with a core containing ascorbic acid whose color is affected by both moisture content and ambient temperature was investigated.

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