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Thus, the buffering capacity depends on the composition of the buffer, i.e. on the concentration of the salt a or b. The maximum value found by differentiation of Eq. (1.4.27) with respect to a corresponds, for an acidic buffer, to b = \s. For practical purposes, a number of buffer mixtures have been proposed that are useful for various pH ranges. Procedures for their preparation and requirements on purity and definition of the chemicals used are given in laboratory manuals and tables. If the solvent is not protogenic but protophilic (acetone, dioxan, tetrahydrofuran, dimethylformamide, etc.), self-ionization obviously does not occur. Consequently, the dissolved acids are dissociated to a greater or lesser degree but dissolved bases do not undergo protolysis. Thus, there can exist only strong acids but no strong bases in these solvents. The pH is not defined for a solution that does not contain a dissolved acid (i.e. in the pure solvent or in the solution of a base). The pKA value can be defined but not

IsXMLRoot( object)

XmlChildPos()

Returns an integer containing the position of the indexed element named the same as childName in xmlelement s XMLChildren array.

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58 the pKB value, and there is no neutral point. If the solvent is neither protogenic nor protophilic, then neither dissolved acids nor dissolved bases are protolysed. Protolytic reactions can occur in such a solvent, but only between dissolved acids and bases (that are not mutually conjugate). If the dielectric constant of an amphiprotic solvent is small, protolytic reactions are complicated by the formation of ion pairs. Acetic acid is often given as an example (denoted here as AcOH, with a relative dielectric constant of 6.2). In this solvent, a dissolved strong acid, perchloric acid, is completely dissociated but the ions produced partly form ion pairs, so that the concentration of solvated protons AcOH2+ and perchlorate anions is smaller than would correspond to a strong acid (their concentrations correspond to an acid with a pK'A of about 4.85). A weak acid in acetic acid medium, for example HC1, is even less dissociated than would correspond to its dissociation constant in the absence of ion-pair formation. The equilibrium HC1 + AcOH AcOH 2 + Cr * AcOH2+ + Cl" is established. If the constants

XmlChildPos( xmlelement, childName, index)

An XML document object element. The name of a child of xmlelement. The indexth occurrence of childname inside xmlelement.

The name of this effect makes it seem less useful than the multi-tap delay, but the simple delay (shown previously in 11, Figure 11-13) has some attractive features that make it an extremely useful tool. The ability to easily create delays that are tempo-dependent makes the simple delay rhythmic and musical. Creating delays on only a portion of the signal was covered in 11, but if you want to add a delay effect on the entire signal, simply use it as an insert effect instead of a bus effect and turn up the dry level. You can also enter the delay and decay times in seconds rather than in musical durations if you want to. But the simple delay really shines with the tempo sync delay checkbox checked. You can soften the abrupt ending of a track, as you learned in 11, and you can create interesting rhythms on percussive material. Using musically significant delay times prevents your mix from getting as muddy as it would with imprecisely timed delays.

(1.4.28)

XmlElemNew()

Returns a new element created inside of xmlObject. After creating the element, it must be assigned to a specific position in the document object.

home yet. You must explicitly specify where the new element is in the hierarchy before it is truly part of the document object.

[AcOH 2 + Cr] [HC1] [AcOH2+Cl~] [AcOH 2 + ][Cr] [AcOH 2 + ][Cr] [HC1] + [AcOH 2 + Cr]

XmlFormat()

Reverb is actually a form of delay. If you are in a space where there are so many reflected sounds that they seem to smear together and you no longer can hear them individually, you ve left the realm of the delay/echo and entered the world of reverb. An echo is like yelling into the Grand Canyon, and hearing a clear voice hollering back at you a bit later. Reverb is like yelling

Returns a string escaped so that it may be used inside an XML element. Replaces any special characters with their XML-safe equivalents.

are introduced, then (1.4.30) The protolytic reaction between two molecules must be formulated as the formation of the pair B + HA^BH+A~ (1.4.31) that can react as a base with another acid HA,, or as an acid with another base B n : B,H + Ar + HA n <P* B,H + A,r + HA, BjH+Ar + B n ^ B u H + A r + Bj ' '

XmlFormat( string)

XmlNew()

XmlNew( caseSensitive)

Protolytic reactions can also occur in fused salts. The solvent participates in these reactions provided that at least one of its ions has protogenic and/or protophilic character. An example of a solvent in which the cation is aprotic and the anion protophilic is ethylpyridinium bromide (m.p. 114 C). The acid HA is protolysed in this solvent (HA + B r ~ ^ H B r + A"). Hydrogen bromide acts as a solvated proton and the acidity is expressed as

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