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62 actually true if acids or bases are compared in a single solvent For example, in aqueous solutions values of KA of 138 x 1(T3, 174 x 10~5 and 427 x 10~7 have been found for chloroacetic acid, acetic acid and carbonic acid, respectively; consequently, in (dilute) aqueous solutions chloroacetic acid is two orders of magnitude stronger than acetic acid which is again two orders stronger than carbonic acid These values have no absolute significance They change on transfer to another solvent and even their order can change If, for example, the protolytic reaction CH3COOH + H2O < * = CH3COO~ + H 3 O + occurred in acetic acid medium, with water as a dissolved base, then the standard state to which the activities and equilibrium constants are related would be changed Comparison of the acidity or basicity of solvents is just as difficult.

Describes the parameters to be passed to the called page. (POSTs only).

<CFHTTPPARAM name = nameOfParam type = URL | FORMFIELD | COOKIE | CGI | FILE value = #valueToSend# file = fullPathToFileToSend > Cross References

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For example, alcohols react according to the equation ROH +H 3 O + ^ ROH 2 + + H2O In dilute solutions (water concentration of less than 1 mol dm" 3 ), the constant K' for this reaction in methanol is equal to 86 x 10~3 and in ethanol, 39 x 10~3 If these values were also valid in the vicinity of composition [ROH]/[H2O] = 1, then the ratio [ROH2+]/[H3O+] = /T[ROH]/[H2O] describing the proton distribution between the alcohol and water would be small Consequently, water would have a greater affinity for protons than alcohol, ie would be more basic The opposite is true The effect of the medium (solvent) on the dissolved substance can best be expressed thermodynamically Consider a solution of a given substance (subscript i) in solvent s and in another solvent r taken as a reference.

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FIGURE 10-23: The Spectral view of the panned rhythmic pattern from Figure 10-6

Water (w) is usually used as a reference solvent The two solutions are brought to equilibrium (saturated solutions are in equilibrium when each is in equilibrium with the same solid phase the crystals of the dissolved substance; solutions in completely immiscible solvents are simply brought into contact and distribution equilibrium is established) The thermodynamic equilibrium condition is expressed in terms of equality of the chemical potentials of the dissolved substance in both solutions, jU,(w) =.

Places a registered Java applet on the page. Any applet referenced by using CFAPPLET must be registered in ColdFusion Administrator.

<CFAPPLET appletSource = nameOfRegisteredApplet name = nameOfFormVariable height = 300 width = 400 vSpace = 10

Applies only if the method was supplied as the applet was registered with ColdFusion Administrator.

The new edition of Principles of Electrochemistry has been considerably extended by a number of new sections, particularly dealing with 'electrochemical material science' (ion and electron conducting polymers, chemically modified electrodes), photoelectrochemistry, stochastic processes, new aspects of ion transfer across biological membranes, biosensors, etc. In view of this extension of the book we asked Dr Ladislav Kavan (the author of the section on non-electrochemical methods in the first edition) to contribute as a co-author discussing many of these topics. On the other hand it has been necessary to become less concerned with some of the 'classical' topics the details of which are of limited importance for the reader. Dr Karel Micka of the J. Heyrovsky Institute of Physical Chemistry and Electrochemistry has revised very thoroughly the language of the original text as well as of the new manuscript. He has also made many extremely useful suggestions for amending factual errors and improving the accuracy of many statements throughout the whole text. We are further much indebted to Prof. Michael Gratzel and Dr Nicolas Vlachopoulos, Federal Polytechnics, Lausanne, for valuable suggestions to the manuscript. During the preparation of the second edition Professor Jiff Dvorak died after a serious illness on 27 February 1992. We shall always remember his scientific effort and his human qualities. Prague, May 1992 Jifi Koryta

hSpace = 10 align = TOP | LEFT | BOTTOM | BASELINE | TEXTTOP | ABSBOTTOM | MIDDLE | ABSMIDDLE | RIGHT notSupported = messageIfNoJava ... > Cross References

Imports a custom tag library and assigns it a tag prefix. Can import JSP custom tags based on a JAR or TLD file; can also import ColdFusion custom tags if given the name of a directory.

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