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changes observed for the amide I band of CiT4 in the presence of TFE: there is a notable change in the shape of the amide I band and six component bands are observed. The small component at 1610 cm 1 occurs in the wavenumber range normally attributed to side-chain contributions. The components at 1623 and 1637 cm 1 are assigned to a low-frequency -structure, with a high-frequency component of the -structure also observed at 1675 cm 1 . These bands contribute to 43% of the total band area. The component in Figure 7.9 observed at 1655 cm 1 , contributing to 21% to the total amide I band area, is assigned to the -helix. The remaining components at 1661 and 1689 cm 1 have been assigned to turns and bends in the peptide secondary structure. Thus, on addition of TFE, a more structured conformation of CiT4 is indicated. Notably, -helical structures and -structures appear to be formed in the less polar environment provided by TFE.

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increased only by applying pressure over her sinuses, I believed this pain was due to chronic sinusitis. She related that she was aware this pain could be relieved with decongestants. We discussed her seeing her primary medical provider for this. She wanted to delay this and asked me to prescribe her a decongestant to be used when she had the pain, which I did.

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The agents we were working with suggested topics of conversation for Oleg to engage Dmitri in, and they had him ask about other schemes in which Dmitri may have been involved. They tried to collect enough details about his life to nd him, prosecute him for this case and prevent him from committing similar ones in the future. Oleg and Dmitri stayed in contact for months. At one point, agents had narrowed down Dmitri s location to one area in Russia and were working with the Russian equivalent of the Secret Service the Federal Security Service of the Russian Federation to gather more evidence. I had to e-mail the Russian agent numerous times to explain the case, details and loss. Honestly, I had not heard of the Russian agency before, so I looked it up online to see if it was legitimate. The Secret Service agent I was collaborating with assured me that they were the good guys. The Secret Service also met with them in Russia to try to bring about the prosecution of Dmitri. The Russian Federation requested formal written letters from Arch Bank to explain the cause, the loss and why they should get involved. Ultimately, they said that although they wanted to prosecute Dmitri, he had a connection to the government, and they could not proceed. They did not explain the situation to us, and it seemed like something out of an old movie. We had hit a wall. In August, only 10 months after the crime began, Oleg pleaded guilty to fraudulent use of an access device. He was sentenced to 12 months of incarceration, ve years of probation and to pay restitution of $20,000. To date, he has paid about $13,000.

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During these two months I had analyzed attempts to take over customers accounts I listened to the calls and checked the phone numbers, but they were made from mobile phones The numbers were registered to ctitious people and were only used once or twice before the telephones were dumped I had nearly exhausted my investigation methods, and was about to hand over the case to the authorities However, during a routine check of the phone number used to change login credentials of one of our customers, I noticed it was not a mobile number This meant a lot there was a good chance this was going to give us a fraudster s address In a few minutes I knew the address from which the call was made The apartment was located close to downtown and was registered to Ruben Abovyan.

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