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(see Section 552), cumene (see Section 553), and xylenes (see Section 554) Research still continues to explore new, recyclable solid materials with better catalyst performance 73 In fact, new commercial processes using large-pore zeolites, such as USY, zeolite Beta, and MCM-22, were developed and commercialized for the manufacture of ethylbenzene The MCM-22 catalyst applied in the Mobil EBMax process is substantially more selective than the other two catalysts (89% selectivity of ethylbenzene at greater than 95% conversion of ethylene) 74 This excellent selectivity is due to the 12-ring pore system and the facile desorption of ethylbenzene from the surface pockets of MCM-22 A new study shows that alkylation takes place on the external surface of the catalyst 375 A new process for the manufacture of p-diethylbenzene developed by Indian Petrochemicals Corporation was commercialized.

376 p-Diethylbenzene is produced by alkylating ethylbenzene with ethanol over a highly shape-selective, poresize-regulated, high-silica zeolite The catalyst exhibits a steady activity of 6-8% conversion with 97-98% selectivity New studies with zeolites were reported; the main concern was selectivity improvements Regioselective dialkylation of biphenyl and naphthalene are of interest because the corresponding dicarboxylic acids prepared from 4,4-disubstituted biphenyls and 2,6-disubstituted naphthalenes are used to manufacture commercially valuable polyesters High selectivities were achieved in the shape-selective isopropylation of biphenyl with propylene to form 4,4-diisopropylbiphenyl over H-mordenites having high Si : Al ratios 77-379 On these samples alkylation proceeds in the pores and transition state control ensures high selectivity When the Si : Al ratio is low, the concentration of surface sites with strong acidity is high, resulting in enhanced coke formation Coke deposition blocks the pore entrance and, therefore, nonselective alkylation occurs on the external surface of the catalyst.

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3. Make sure that the page element selected is represented in the Link field. If no selection is made, Dreamweaver creates a new Detail text link. 4. Enter the path to the detail page in the Detail Page field or click Browse to locate the file in the Select File dialog box.

Highly regioselective dialkylation of naphthalene was performed with 2-propanol 38o and tert-butyl alcohol38J over dealuminated H-mordenite, and with tert-butyl alcohol over HY and Beta zeolites 82 Selectivities are within 60-84% Computational modeling showed that the kinetic diameter of the 2,6-disubstituted isomer is smaller than that of the 2,7 isomer, which may explain the selective formation of the former within the appropriate zeolitic framework 82 Clays are efficient electrophilic catalysts and were applied in Friedel-Crafts alkylations In most studies KlO montmorillonite, an acid-treated bentonite, was used The catalytic activity of clays can be further enhanced by various modifications Ion exchange with F3+ or Zn 2+ brings about outstanding catalytic properties Pillaring is another possibility to modify the properties of clay materials Pillared clays (PILCs) exhibit a microporous structure and acidic properties that make them suitable for application in Friedel-Crafts alkylations.

The first method calculates the slope and intercept separately, using the functions SLOPE() and INTERCEPT(). The second and third use two functions that

Clays pillared with F3+ gave alkylated products in the reaction of alkylbenzenes with benzyl chloride with nearquantitative conversion 83 With toluene, monomethylation without the formation of the meta isomer was observed Materials pillared with Al13 and GaAl 12 polyoxocations showed high catalytic activity in the alkylation of toluene with methanol yielding xylenes with 60% and 74% selectivities, respectively 84.

The design view in Catalyst shows you exactly what your final project will look like. Because your project will run in Flash Player, which also renders projects in exactly the same way regardless of the operating system or browser through with it is playing, you can be sure that the design you see in Catalyst is what your users will see. Despite this, you will still want to run your project and view it in Flash Player in a browser. Primarily, this allows you to test interactive elements. Scrollbars, for example, don t work in the Catalyst design view; you must run the project in order to test them. You can run a project by choosing File Run Project (see Figure 4.21) or by pressing Ctrl+Enter ( +Enter). When you do so, Catalyst compiles the project, opens your computer s default browser, and launches the project (see Figure 4.22). Because it must compile the project before running, this process may take a few seconds to complete.

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