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are common examples of crevices. Inside the crevice, oxygen or other corrosives required for passivation have restricted entrance, resulting in reduced concentration as they are consumed by corrosion in the crevice. When the concentration of these corrosives is low enough to fail to maintain passivity, the metal in the crevice becomes active. The large electrically connected, passivated surface outside the crevice completes a galvanic couple with a large adverse-area ratio, providing high attack rates within the crevice. Welding or forming can be used to avoid crevices. However, intergranular corrosion may occur in welded stainless steels (see Sec. 35.3.9). Pitting is a very localized attack that results in holes, or voids, on a metal surface. Although not restricted to active-passive metals, pitting is commonly related to these. With active-passive metals, pieces of dirt, scale, or other solid particles may rest on the bottom of a pipe or tank where velocities are not sufficient to move them. These particles form crevices, resulting in a localized attack similar to crevice corrosion.

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35.3.5 Sacrificial Anodes Magnesium rods are placed in steel glass-lined hot-water tanks, and zinc is used to coat sheet steel (galvanized steel) to provide protection to the steel against corrosion. As the more active magnesium rod is attacked, the electrons generated are conveyed to the electrically connected steel tank, which needs protection only for regions where cracks or flaws exist in the glass lining. Similarly, for galvanized steel, protection is required only for regions of scratches or where steel edges are exposed.

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35.3.6 Stress Corrosion Cracking In stress corrosion cracking (SCC), most of a metal s surface may show little attack, while fine intergranular or transgranular cracks may penetrate deeply into the surface. There may be a single continuous crack or a multibranched crack, or the entire surface may be covered with a lacy network of cracks. Usually dye penetrants and sectioning are needed to reveal the extent and depth of cracking. Certain classes of alloys and environments are susceptible to this phenomenon, and usually tensile stresses are involved, with crack penetration rates increasing with increasing tensile stress. The higher the strength condition of a given alloy, the greater seems to be the tendency to suffer SCC. Table 35.3 lists some materials and environments that have been known to produce SCC. Frequently, a difference in color or texture is noticeable between a stress corrosion crack and an adjacent region of overstress when the fracture is completed by mechanical means. Scanning electron micrographs are frequently useful in identifying SCC.

35.3.7 Selective Leaching Selective leaching refers to the chemical removal of one metal from an alloy, resulting in a weak, porous structure. Brass sink traps suffer this type of attack by zinc being leached out of the yellow brass, leaving behind a porous structure of reddish copper. Aluminum and silicon bronzes and other alloys are also subjected to selective leaching.

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35.3.8 Hydrogen Embrittlement In any electrochemical process where hydrogen ions are reduced, monatomic hydrogen atoms are created prior to their joining in pairs to form diatomic hydrogen gas (H2). Monatomic hydrogen, being small, can diffuse into metals, causing embrittlement. Corrosion of metals by acids, including cleaning by pickling, can produce hydrogen embrittlement. Heating can drive out monatomic hydrogen, reversing the process. If monatomic hydrogen diffuses into voids in a metal, high-pressure pockets of H2 gas are formed which are not eliminated by heating, but rather may form hydrogen blisters.

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