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TRPCal values calculated from Tv (Td ) values and from Tig values are signi cantly different. The TRPCal values are in general lower than the TRPExp values, as shown in Figure 11.5 (TRPCal values from Tv (Td ) values for highly halogenated polymers are not included as they are signi cantly lower than the Tig values). The data in Figure 11.5 show that TRPCal values are about 24% lower than the TRPExp values. It thus appears that the purely thermal arguments based on the ignition relationship in Eq. (11.6) is not suf cient to account for the ignition behavior of polymers. There is a need to incorporate the chemical arguments for the ignition behavior of polymers. Currently there is lack of understanding of the chemical effects on the ignition behavior of polymers. The experimental conditions, therefore, cannot be controlled precisely, and the effects are apparent in the lack of repeatability in the ignition time measurements, especially for polymers where chemical effects are stronger, such as the high-temperature and highly halogenated advanced engineered polymers. Also a better understanding of the chemical effects on the ignition behavior of polymers would lead to the development of more effective re-retardant/ re-hardening agents for the polymers.
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69 DeVilliers, M M, van der Watt, J G, and Lotter, A P (1992), Kinetic study of the solidstate photolytic degradation of two polymorphic forms of furosemide, Int J Pharm, 88, 275 283 70 Nakagawa, Y, Itai, S, Yoshida, T, and Nagai, T (1992), Physicochemical properties and stability in the acidic solution of a new macrolide antibiotic, clarithromycin, In comparison with erythromycin, Chem Pharm Bull, 40, 725 728 71 Pikal, M, and Lukes, A L (1976), Kundsen vapor pressure measurements on pure materials and solutions dispersed in porous media: Molded nitroglycerin tablets, J Pharm Sci, 65, 1269 72 Fusari, S A (1973), Nitroglycerin sublingual tablets II: preparation and stability of a new stabilized sublingual molded nitroglycerin tablet, J Pharm Sci, 62, 2012 73 Finholt, P, Jurgensen, G, and Kristiansen, H.
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variables, and its goals must be incomplete. Semioticians call this loop the loop of semiosis. In this loop the process of learning and interpretation is run, and the convergence of it should be achieved. Thus, as we reason about the world and its processes, the property of closure should be satis ed. Thus, as we construct a simulation system, the property of closure should also be satis ed. In Figure 11.10, a structure of closure is shown as an ELF for the case of intelligent controller simulated functioning. The modules actuators-world-sensors are to be substituted by a simulation system that receives control commands from the intelligent controller and generates simulated sensor inputs for it. For a simulation system, the components of a system s functioning associated with value judgment should be explicated and made available for observation. Certainly, the functioning of ELF s modules can be described adequately only if ELFs can be constructed for its modules, too. An ELF within an ELF is shown in Figure 11.11 for the behavior generation module. 11.9.4. The World is Not Flat: It is Multi-resolutional! Through the millenia, people used to bene t from the phenomena of larger and smaller pictures, like bird s-eye view, and so on. However, only recently we have arrived at the scienti c awareness of the following: We see the same things and recognize different objects and phenomena depending on the spatial and temporal resolution of our interest. Mandelbrot s (1982) fractals came as a surprise, because suddenly it was realized that at different scales there is always more than the unequipped eye can see. All signs pertain to some particular scale of consideration. Semiotics offers its views also in scales: It is a multiscale, or multiresolutional phenomenon, too (Meystel, 1995c).
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